Solving the challenging synthesis of highly cytotoxic ...
The use of ball-mills enabled the straightforward synthesis of a variety of silver(I) complexes featuring challenging NHC ligands.Sterically hindered including electron-poor or with very low solubility imidazolium salts were ground with silver(I) oxide to furnish heteroleptic or homoleptic complexes in high yields and short reaction times.The synthesis of heteroleptic bis-NHC silver(I ...